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While at pH value greater than 6.5, the decrease might be due increased ionization of GSH which made the non-enzymatic rate product formation much rapid to upset the enzymatic rate

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It consists of three amino acidsglycine, cysteine, and glutamic acid and offers a range of health benefits such as liver detoxification, improved immune system function, and powerful antioxidant defense

doi: 10.1371/journal.pone.0198626